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Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supports

Four silica samples were evaluated as supports in the hydroformylation of oct-1-ene by Supported Aqueous Phase Catalysis (SAPC) using [Rh2(µ-StBu)2(CO)2(TPPTS)2] and [Rh(COD)Cl]2/TPPTS as catalysts. Adsorption studies of the [Rh(COD)Cl]2/TPPTS co...

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Autores Principales: Jáuregui-Haza,U. J., Wilhelm,A. M., Delmas,H.
Formato: Online
Idioma:English
Publicado: Latin American applied research 2002
Acceso en línea:http://bibliotecadigital.uns.edu.ar/scielo.php?script=sci_arttext&pid=S0327-07932002002200003
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id bda_laar-S0327-07932002002200003
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spelling bda_laar-S0327-079320020022000032002-04-01Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supportsJáuregui-Haza,U. J.Wilhelm,A. M.Delmas,H. Supported Aqueous-Phase Catalysis (SAPC) hydroformylation oct-1-ene silica rhodium Four silica samples were evaluated as supports in the hydroformylation of oct-1-ene by Supported Aqueous Phase Catalysis (SAPC) using [Rh2(µ-StBu)2(CO)2(TPPTS)2] and [Rh(COD)Cl]2/TPPTS as catalysts. Adsorption studies of the [Rh(COD)Cl]2/TPPTS complex from aqueous solutions on the supports were carried out at 25 °C. The isotherms obtained were correlated by several models, among which the Fowler-Guggenheim/Jovanovic-Freundlich equation was found to be the most satisfactory. The influence of the nature of catalytic complex and of the methods for supporting the catalyst on the silica conversion was also studied.Latin American applied research2002-04-01journal articletext/htmlhttp://bibliotecadigital.uns.edu.ar/scielo.php?script=sci_arttext&pid=S0327-07932002002200003en
institution UNS
collection Biblioteca Digital Académica
building Biblioteca Central
bda_str Latin American Applied Research
hierarchy_parent_id bda_laar
hierarchy_parent_title Latin American Applied Research
hierarchy_top_id bda_str
hierarchy_top_title Biblioteca Digital Académica
first_indexed 2018-08-22T17:39:27Z
last_indexed 2018-08-22T17:39:27Z
language English
format Online
author Jáuregui-Haza,U. J.
Wilhelm,A. M.
Delmas,H.
spellingShingle Jáuregui-Haza,U. J.
Wilhelm,A. M.
Delmas,H.
Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supports
author_facet Jáuregui-Haza,U. J.
Wilhelm,A. M.
Delmas,H.
author_sort Jáuregui-Haza,U. J.
title Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supports
title_short Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supports
title_full Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supports
title_fullStr Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supports
title_full_unstemmed Hydroformylation of oct-1-ene by supported aqueous phase catalysis: Influence of catalytic complex and preparation method of the supports
title_sort hydroformylation of oct-1-ene by supported aqueous phase catalysis: influence of catalytic complex and preparation method of the supports
topic_facet Supported Aqueous-Phase Catalysis (SAPC)
hydroformylation
oct-1-ene
silica
rhodium
description Four silica samples were evaluated as supports in the hydroformylation of oct-1-ene by Supported Aqueous Phase Catalysis (SAPC) using [Rh2(µ-StBu)2(CO)2(TPPTS)2] and [Rh(COD)Cl]2/TPPTS as catalysts. Adsorption studies of the [Rh(COD)Cl]2/TPPTS complex from aqueous solutions on the supports were carried out at 25 °C. The isotherms obtained were correlated by several models, among which the Fowler-Guggenheim/Jovanovic-Freundlich equation was found to be the most satisfactory. The influence of the nature of catalytic complex and of the methods for supporting the catalyst on the silica conversion was also studied.
publisher Latin American applied research
publishDate 2002
url http://bibliotecadigital.uns.edu.ar/scielo.php?script=sci_arttext&pid=S0327-07932002002200003
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score 12,614403

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